CONVENIENT PREPARATIONS OF 2,3-DIHYDRO-4H-PYRAN-4-ONES FROM D-GLUCAL TRIACETATE - SELECTIVE OXIDATIONS OF ALYLLIC ACETATES AND ALLYLIC SILYL ETHERS USING N-BROMOSUCCINIMIDE

被引：10

作者：

BOUILLOT, A ^{[1
]}

KHAC, DD ^{[1
]}

FETIZON, M ^{[1
]}

GUIR, F ^{[1
]}

MEMORIA, Y ^{[1
]}

机构：

[1] ECOLE POLYTECH,SYNTHESE ORGAN LAB,F-91128 PALAISEAU,FRANCE

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 15期

关键词：

D O I：

10.1080/00397919308018600

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Bromosuccinimide (1.1 eq) in the presence of potassium carbonate (2 eq) and a catalytic amount of dibenzoyl peroxide converts the allylic acetates and the allylic silyl ethers (O-TBDMS or O-SiEt3) of secondary allylic alcohols, derived from D-glucal 3a into corresponding dihydro gamma-pyrones 2.

引用

页码：2071 / 2081

页数：11

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