CRYSTAL-STRUCTURE OF POLY[(TRIS-MU-IODO-BIS-LESS-THAN(2,2',2''-NITRILODIETHOXYETHANOL)DILEAD(II)GREATER-THAN)-MU-IODO] OBTAINED BY DIRECT-METHODS USING LEAD(II) OXIDE AS A STARTING MATERIAL

被引：14

作者：

KOKOZAY, V

SIENKIEWICZ, A

机构：

[1] Department of Chemistry, University of Kiev, Kiev

来源：

POLYHEDRON | 1993年 / 12卷 / 19期

关键词：

D O I：

10.1016/S0277-5387(00)83063-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A direct method of obtaining (Pb4I4L2)n, where L is twice deprotonated 2,2',2''-nitrilotriethanol (triethanolamine), is reported. The crystal structure of the compound was determined by X-ray techniques. The crystallographically independent fragments of Pb4I4L2 are associated by bridging oxygen and iodine atoms in endless layers parallel to the bc-plane of the crystal. Tetradentate twice deprotonated triethanolamine is coordinated to lead(II) via oxygen and nitrogen atoms.

引用

页码：2421 / 2423

页数：3