HYDROGENATION OF BIPHENYLS OVER THE HYDROGEN STORAGE ALLOY MMNI(3.5) CO0.7AL0.8H4

被引：4

作者：

NAKAGAWA, S

MURATA, S

SAKAI, T

NOMURA, M

机构：

[1] OSAKA UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 565, JAPAN

[2] GOVT IND RES INST, OSAKA 563, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 03期

关键词：

D O I：

10.1246/cl.1994.431

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogenation of biphenyl with the activated hydrogen storage alloy, MmNi(3.5)Co(0.7)Al(0.8)H(4) (Mm: La, 30; Ce, 52; Pr, 5; Nd, 13 wt%) as a stoichiometric reductant proceeded effectively at 160 degrees C for 3 h under nitrogen to give either phenylcyclohexane or bicyclohexyl selectively, according to the ratio of the alloy to biphenyl.

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页码：431 / 432

页数：2

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