ON THE POSSIBLE ELECTRONIC INSTABILITY OF THE MONOPHOSPHATE TUNGSTEN BRONZE (WO3)4(PO2)4

被引:16
作者
CANADELL, E [1 ]
WHANGBO, MH [1 ]
机构
[1] N CAROLINA STATE UNIV,DEPT CHEM,RALEIGH,NC 27695
关键词
D O I
10.1016/0022-4596(90)90124-G
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The electronic structure of the monophosphate tungsten bronze (WO3)4(PO2)4 was examined by performing tight-binding band calculations. Our study suggests that the W2O10 chains of (WO3)4(PO2)4 have both localized and delocalized electrons, and the latter may cause an electronic instability such as a charge density wave. © 1990.
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页码:131 / 134
页数:4
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