THE ZR6CL12(PME2PH)6 MOLECULE REVISITED - A DIRECTED SYNTHESIS

被引：11

作者：

COTTON, FA ^{[1
]}

WOJTCZAK, WA ^{[1
]}

机构：

[1] TEXAS A&M UNIV,MOLEC STRUCT & BONDING LAB,COLLEGE STN,TX 77843

来源：

INORGANICA CHIMICA ACTA | 1994年 / 223卷 / 1-2期

关键词：

CRYSTAL STRUCTURES; ZIRCONIUM COMPLEXES;

D O I：

10.1016/0020-1693(94)03996-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new method for preparing the compound formally assigned the composition Zr6Cl12(PMe2Ph)6 is described. The compound can now be obtained reproducibly in about 16% yield. A new crystalline form was obtained and fully characterized by X-ray crystallography, giving molecular dimensions in essential a agreement with those previously reported. Crystal data: space group, P1BAR with a = 19.032(4), b = 13.328(2), c = 14.401(2) angstrom, alpha = 92.69(1), beta = 92.18(2), gamma = 108.01(3)-degrees, V = 3464(2) angstrom3, Z = 2. The possibility that hydrogen atoms may be attached to each of two faces of the Zr6 octahedron is suggested and discussed.

引用

页码：93 / 95

页数：3

共 5 条

[1] EMPTY OCTAHEDRAL HEXAZIRCONIUM CLUSTERS WITH ONLY 10 ELECTRONS, [ZR6X14(PR3)4]
COTTON, FA
FENG, XJ
SHANG, MY
WOJTCZAK, WA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (08): : 1050 - 1053
[2] SYNTHESIS BY SPONTANEOUS SELF-ASSEMBLY OF METAL ATOM CLUSTERS OF ZIRCONIUM, NIOBIUM, AND TANTALUM
COTTON, FA
KIBALA, PA
ROTH, WJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (01) : 298 - 300
[3] PENTANUCLEAR ZIRCONIUM CLUSTERS WITH CHLORIDE, HYDRIDE, AND PHOSPHINE-LIGANDS
COTTON, FA
LU, J
SHANG, MY
WOJTCZAK, WA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (10) : 4364 - 4369
[4] COTTON FA, IN PRESS
[5] CENTERED ZIRCONIUM CHLORIDE CLUSTERS - SYNTHETIC AND STRUCTURAL ASPECTS OF A BROAD SOLID-STATE CHEMISTRY
ZIEBARTH, RP
CORBETT, JD
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1989, 22 (07) : 256 - 262

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