THE SYNTHESIS AND PROPERTIES OF HETERODINUCLEAR ALKANEDIYL COMPLEXES OF IRON(II) CONTAINING MOLYBDENUM(II), TUNGSTEN(II), RHENIUM(I) AND RUTHENIUM(II)

被引：24

作者：

FRIEDRICH, HB ^{[1
]}

MOSS, JR ^{[1
]}

WILLIAMSON, BK ^{[1
]}

机构：

[1] UNIV CAPE TOWN,DEPT CHEM,RONDEBOSCH 7700,SOUTH AFRICA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 394卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(90)87241-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the iodoalkyl compounds [(η5-C5R5)Fe(CO)2{(CH2)nI}] with Na[MLy] yield the new heterodinuclear alkanediyl compounds [(η5-C5R5)-(CO)2Fe(CH2)nMLy] (where R = H: MLy = Mo(CO)3Cp, W(CO)3Cp, Re(CO)5, n = 3-6; R = CH3: MLy = Ru(CO)2Cp, n = 3-5; Re(CO)5, n = 4). The related mixed ligand complex [Cp(CO)2Fe(CH2)3Fe(CO)2CP{black star}] has also been prepared (where Cp = η5-C5H5 and Cp{black star} = η5-C5(CH3)5). The new compounds have been fully characterised by analytical and spectroscopic methods. © 1990.

引用

页码：313 / 327

页数：15

共 19 条

[1] REACTIONS OF METALLABROMOALKANES [M((CH2)NBR)(CO)3(ETA-C5H5)] (M=MOORW,N=3OR4) WITH TRANSITION-METAL ANIONS - DIMETALLAALKANE AND CYCLIC CARBENE COMPLEX-FORMATION - CRYSTAL AND MOLECULAR-STRUCTURES OF [(ETA-C5H5)(OC)3MO((CH2)4)MO(CO)3(ETA-C5H5)] AND [(ETA-C5H5)(OC)3MOW(CO)2(C-O-(CH2)2CH2)(ETA-C5H5)]
ADAMS, H
BAILEY, NA
WINTER, MJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (02): : 273 - 278
[2] ADAMS RD, 1988, POLYHEDRON, V7, P2251
[3] ARCHER SJ, UNPUB S AFR J CHEM
[4] SELECTIVE DIHYDROGEN ADDITION TO IRIDIUM IONS IN POLYNUCLEAR COMPLEXES DERIVED FROM THE METALLOMACROCYCLES M2(CO)2CL2((MU-PH2PCH2)2ASPH)2 (M = IR OR RH)
BALCH, AL
DAVIS, BJ
NEVE, F
OLMSTEAD, MM
[J]. ORGANOMETALLICS, 1989, 8 (04) : 1000 - 1007
[5] THE METALLOPHOSPHINE PH2PW(CO)3CP AS PRECURSOR OF THE PH2PW(CO)2CP FRAGMENT - ITS ETHYLENE-LIKE DISPLACEMENT FROM ITS COMPLEXES WITH PLATINUM(0)
BRAUNSTEIN, P
DEJESUS, E
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 365 (03) : C19 - C22
[6] ORGANIC-CHEMISTRY OF DINUCLEAR METAL CENTERS .5. GENERATION OF HYDROCARBONS FROM METHYLENE CHAINS LINKING 2 METAL CENTERS - EVIDENCE FOR A DIMETALLACYCLE INTERMEDIATE
COOKE, M
FORROW, NJ
KNOX, SAR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (11): : 2435 - 2440
[7] CHEMISTRY OF POLYNUCLEAR METAL-COMPLEXES WITH BRIDGING CARBENE OR CARBYNE LIGANDS .95. SYNTHESIS AND CRYSTAL-STRUCTURES OF [W2RUPT(MU-CC6H4ME-4)-(MU-3-CC6H4ME-4)(CO)6(PME2PH)(ETA-C5H5)2] AND [W2RU2PT2(MU-3-CC6H4ME-4)2(MU-CO)2(CO)9(ETA-C5H5)2]
DAVIES, SJ
HOWARD, JAK
PILOTTI, MU
STONE, FGA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (11): : 2289 - 2296
[8] ORGANO PLATINUM IRON COMPLEXES DERIVED FROM ALLENES - CRYSTAL-STRUCTURES OF [(OC)3FE(MU-DPPM)(MU-C(O)CH2C(=CH2))PT(PPH3)], [(OC)3FE(MU-DPPM)-(MU-C(=CH2)CH2)PT(PPH3)], AND [(OC)2FE(MU-DPPM)(ETA-4-(CH2)(CME2)CPT(PPH3))]
FONTAINE, XLR
JACOBSEN, GB
SHAW, BL
THORNTONPETT, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (05): : 1185 - 1192
[9] HALOGENOALKYL COMPLEXES OF THE TRANSITION-METALS .7. THE SYNTHESIS AND PROPERTIES OF THE OMEGA-HALOGENOALKYL COMPLEXES [(ETA-C5R5)(CO)2FE(CH2)NX] (R = H, N = 3-10, X = BR, I-R = CH3, N = 3-5, X = BR, I)
FRIEDRICH, HB
MAKHESHA, PA
MOSS, JR
WILLIAMSON, BK
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 384 (03) : 325 - 338
[10] RAPID, REVERSIBLE INTRAMOLECULAR C-H OXIDATIVE ADDITION AND HYDROGEN-EXCHANGE IN A HETERODINUCLEAR EARLY LATE TRANSITION-METAL COMPLEX
JACOBSEN, EN
GOLDBERG, KI
BERGMAN, RG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (11) : 3706 - 3707

← 1 2 →