SELECTIVITIES IN BIOMIMETIC ATOM ABSTRACTION REACTIONS

被引：19

作者：

KHANNA, RK

PAULING, TM

VAJPAYEE, D

机构：

[1] Department of Chemistry, Biochemistry University of Southern Mississippi, Hattiesburg

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 31期

基金：

美国国家科学基金会;

关键词：

BIOMIMETIC; HYDROXYLATION; OXOMETALLOPORPHYRINS; SELECTIVITIES; ATOM ABSTRACTION;

D O I：

10.1016/S0040-4039(00)79369-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Selectivities of oxometalloporphyrin complexes towards hydrogen atom abstraction from substituted toluenes decrease in the order Cr = O > Fe = O > Mn = O, which is in accord with the force constants of the M = O bonds in these model oxygenases.

引用

页码：3759 / 3762

页数：4

共 24 条

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