SYNTHESIS AND ELECTROCHEMICAL CHARACTERIZATION OF A NEW FAMILY OF LITHIUM-SALTS

被引：26

作者：

BENRABAH, D

SANCHEZ, JY

ARMAND, M

机构：

[1] Laboratoire d'Ionique et d'Electrochimie du Solide, URA 1213, CNRS ENSEEG-INP Grenoble, 38402 Saint Martin d'Hères

来源：

SOLID STATE IONICS | 1993年 / 60卷 / 1-3期

关键词：

D O I：

10.1016/0167-2738(93)90279-C

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper deals with the chemical and electrochemical characterization of a novel lithium salt which has a bulky delocalized anion. This salt has been synthesized with a good overall yield by reacting (CF3SO2)2CHNa with an acid chloride C6H5COCl. The crystallinity of high molecular weight host polymer POE is notably reduced by dissolution of the salt and, at room temperature, some complexes provide the best conductivities known up to now. Furthermore a microvoltammetry study has shown the wide electrochemical window of this salt.

引用

页码：87 / 92

页数：6

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