A NOVEL COMPLEX WITH BOAT-SHAPED, SYNFACIALLY BOUND ETA(3)-ETA(3)-BENZENE BRIDGES AND THE FIRST MU(3)-ETA(2)-ETA(2)-ETA(2)-ARENETRIRHODIUM COMPLEX

被引：39

作者：

MULLER, J

GAEDE, PE

QIAO, K

机构：

[1] Institut für Anorganische und Analytische Chemie, Technischen Universität Berlin, D-10623

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 12期

关键词：

D O I：

10.1002/anie.199316971

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Successive complexation of photolytically generated [CpRh] fragments to benzene affords complexes 1 and 2. The novel structural characteristic of 1 is the bonding of the benzene bridge. It coordinates as two enyl ligand systems, each attached to a different Rh center. Complex 2 is the first example of a face‐capping arrangement of an arene in Rh complexes. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

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页码：1697 / 1699

页数：3

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