SELECTIVE HYDROGENATION OF CYCLIC ESTER TO ALPHA,OMEGA-DIOL CATALYZED BY CATIONIC RUTHENIUM COMPLEXES WITH TRIALKYLPHOSPHINE LIGANDS

被引：38

作者：

HARA, Y ^{[1
]}

INAGAKI, H ^{[1
]}

NISHIMURA, S ^{[1
]}

WADA, K ^{[1
]}

机构：

[1] MITSUBISHI KASEI CORP, RES CTR, 1000 KAMOSHIDA CHO, MIDORIKU KU, YOKOHAMA 227, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 10期

关键词：

D O I：

10.1246/cl.1992.1983

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclic esters like gamma-butyrolactone were smoothly hydrogenated in the presence of a series of ruthenium complexes with trialkylphosphine ligands under mild conditions to afford the correspondig alpha,omega- diols with high selectivity. The ruthenium complexes prepared in the presence of additional NH4PF6 or H3PO4 turned out to have the superior catalytic activity.

引用

页码：1983 / 1986

页数：4

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