CHEMICAL-REACTION ENGINEERING OF COMPLEX-MIXTURES

被引:17
作者
ASTARITA, G [1 ]
OCONE, R [1 ]
机构
[1] PRINCETON UNIV,DEPT CHEM ENGN,PRINCETON,NJ 08544
关键词
D O I
10.1016/0009-2509(92)87031-K
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Recent advances in the description and analysis of chemical kinetics in complex multicomponent mixtures are reviewed. The pitfalls intrinsic to experiments performed on either the real mixture or model compunds are discussed. Describing correctly the kinetics does not, however, exhaust the chemical reaction engineering of such systems, and many open problems are left in the area of reactor configurations other than the batch and plug flow reactor, and in reaction networks with some degree of topological complexity. The methodology of approach to such problems is discussed, and some partial results are presented.
引用
收藏
页码:2135 / 2147
页数:13
相关论文
共 29 条
[1]   ON THEORY OF REACTIONS IN CONTINUOUS MIXTURES [J].
ARIS, R ;
GAVALAS, GR .
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1966, 260 (1112) :351-&
[2]   CONTINUOUS LUMPING OF NONLINEAR CHEMICAL-KINETICS [J].
ARIS, R ;
ASTARITA, G .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 1989, 26 (01) :63-69
[3]  
ARIS R, 1968, ARCH RATION MECH AN, V27, P356
[4]   REACTIONS IN CONTINUOUS MIXTURES [J].
ARIS, R .
AICHE JOURNAL, 1989, 35 (04) :539-548
[5]   ALGEBRA OF SYSTEMS OF SECOND-ORDER REACTIONS [J].
ARIS, R .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1964, 3 (01) :28-&
[6]  
ARIS R, 1991, KINETIC THERMODYNAMI
[7]  
ARIS R, 1991, CHEM REACTIONS COMPL
[8]  
Aris R., 1965, ARCH RATIONAL MECH A, V19, P81, DOI DOI 10.1007/BF00282276
[9]   MULTIPLE STEADY-STATES IN MAXIMUM MIXEDNESS REACTORS [J].
ASTARITA, G .
CHEMICAL ENGINEERING COMMUNICATIONS, 1990, 93 :111-124
[10]   HETEROGENEOUS CHEMICAL-EQUILIBRIA IN MULTICOMPONENT MIXTURES [J].
ASTARITA, G ;
OCONE, R .
CHEMICAL ENGINEERING SCIENCE, 1989, 44 (10) :2323-2331