ETA-CYCLOPENTADIENYL MOLYBDENUM IMIDO COMPOUNDS - HALO, ALKENE, ALKYNE, ALLYL AND TERTIARY PHOSPHINE DERIVATIVES

被引：45

作者：

GREEN, MLH ^{[1
]}

KONIDARIS, PC ^{[1
]}

MOUNTFORD, P ^{[1
]}

SIMPSON, SJ ^{[1
]}

机构：

[1] UNIV SALFORD,DEPT CHEM & APPL CHEM,SALFORD M5 4WT,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 03期

关键词：

D O I：

10.1039/c39920000256

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new imido compounds [M(eta-C5H4R)Cl2(NR')]* (M = Mo, R = H, R' = Bu(t), Pr(n) or Ph; M = Mo, R = Me, R' = Bu(t) or Ph; M = W, R = H, R' = Bu(t)), [Mo(eta-C5H4R)Cl(L)(NR')] (R = H, R' = Bu(t), L = eta-C2H4, or eta-C2Me2; R = Me, R' = Bu(t), L = C2H4*; R = H, R' = Ph, L = eta-C2Me2), [{Mo(eta-C5H4R)(eta-C2H4)(NBU(t))}2Hg]* (R = H, Me), [Mo(NBU(t))Cl2(PMe3)3], [Mo(eta-C5H5)Cl3(NBu(t))] and the pi-allyl complex [Mo(eta-C5H4Me)(eta-C3H5)(eta-C3H5)(NBu(t))] are synthesised; *indicates that the crystal structure has been determined.

引用

页码：256 / 259

页数：4

共 20 条

[1] PLANAR 20-ELECTRON OSMIUM IMIDO COMPLEXES - A LINEAR IMIDO LIGAND DOES NOT NECESSARILY DONATE ITS LONE PAIR OF ELECTRONS TO THE METAL
ANHAUS, JT
KEE, TP
SCHOFIELD, MH
SCHROCK, RR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (04) : 1642 - 1643
[2] ON THE MECHANISM OF OXYGEN ATOM OR NITRENE GROUP TRANSFER IN REACTIONS OF EPOXIDES AND AZIRIDINES WITH TUNGSTEN(II) COMPOUNDS
ATAGI, LM
OVER, DE
MCALISTER, DR
MAYER, JM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (03) : 870 - 874
[3] ORGANOIMIDO-COMPLEXES OF TUNGSTEN-(VI) TUNGSTEN-(V), AND TUNGSTEN-(IV) - CRYSTAL AND MOLECULAR-STRUCTURES OF [W(NPH)CL3(PPH3)2] AND [W(NPH)CL2(PME3)3]
BRADLEY, DC
HURSTHOUSE, MB
MALIK, KMA
NIELSON, AJ
SHORT, RL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (12): : 2651 - 2656
[4] SIR88 - A DIRECT-METHODS PROGRAM FOR THE AUTOMATIC SOLUTION OF CRYSTAL-STRUCTURES
BURLA, MC
CAMALLI, M
CASCARANO, G
GIACOVAZZO, C
POLIDORI, G
SPAGNA, R
VITERBO, D
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1989, 22 : 389 - 393
[5] SURFACE INTERMEDIATES IN SELECTIVE PROPYLENE OXIDATION AND AMMOXIDATION OVER HETEROGENEOUS MOLYBDATE AND ANTIMONATE CATALYSTS
BURRINGTON, JD
KARTISEK, CT
GRASSELLI, RK
[J]. JOURNAL OF CATALYSIS, 1984, 87 (02) : 363 - 380
[6] HOMOGENEOUS MODELS FOR PROPYLENE AMMOXIDATION .2. THE CARBON-NITROGEN BOND-FORMING STEP
CHAN, DMT
NUGENT, WA
[J]. INORGANIC CHEMISTRY, 1985, 24 (10) : 1422 - 1424
[7] HOMOGENEOUS MODELS FOR PROPYLENE AMMOXIDATION .1. TUNGSTEN(VI) IMIDO COMPLEXES AS MODELS FOR THE ACTIVE-SITES
CHAN, DMT
FULTZ, WC
NUGENT, WA
ROE, DC
TULIP, TH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (01) : 251 - 253
[8] ORGANOIMIDO COMPLEXES OF TUNGSTEN(IV) CONTAINING PI-ALKENE AND PI-ACETYLENE LIGANDS - THE X-RAY CRYSTAL-STRUCTURE OF DICHLORO(DIPHENYLACETYLENE)PHENYLIMIDOBIS(TRIMETHYL-PHOSPHINE)TUNGSTEN(IV), [WCL2(NPH)(PHC=CPH)(PME3)2]
CLARK, GR
NIELSON, AJ
RICKARD, CEF
WARE, DC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (06) : 343 - 345
[9] ORGANOIMIDO COMPLEXES OF TUNGSTEN(IV) CONTAINING PI-ACCEPTOR LIGANDS
NIELSON, AJ
WARE, DC
[J]. POLYHEDRON, 1990, 9 (04) : 603 - 610
[10] TRANSITION-METAL COMPLEXES CONTAINING ORGANOIMIDO (NR) AND RELATED LIGANDS
NUGENT, WA
HAYMORE, BL
[J]. COORDINATION CHEMISTRY REVIEWS, 1980, 31 (02) : 123 - 175

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