HTC(N2)(DPPE)2 AS STARTING MATERIAL FOR MIXED-LIGAND COMPLEXES OF TECHNETIUM(I)

被引：11

作者：

KADEN, L

FINDEISEN, M

LORENZ, B

SCHMIDT, K

WAHREN, M

机构：

[1] Central Institute of Isotope and Radiation Research, 0-7050 Leipzig

来源：

INORGANICA CHIMICA ACTA | 1992年 / 193卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)80355-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the complex HTc(N2)(dppe)2 the nitrogen ligand is most labile and can be exchanged under mild conditions for CO, isonitriles and phosphites (L1), yielding neutral hydridocomplexes of Tc(I) HTcL1(dppe)2. HTc(CO)(dppe)2 is also formed from the title compound by CO abstraction from methanol. In the complexes HTcL1(dppe)2 the hydrido ligand can be exchanged for acetonitrile (L2), yielding cationic mixed-ligand complexes of Tc(I) TcL1L2(dppe)2+, which are isolated as hexafluorophosphates.

引用

页码：213 / 215

页数：3

共 13 条

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