SYNTHESIS OF 1,3-DIOXANE-BRIDGED PYROPHEOPHORBIDE-DIIMIDE AND PYROPHEOPHORBIDE DIMER AND THEIR INTRAMOLECULAR ELECTRON AND ENERGY-TRANSFER

被引：38

作者：

OSUKA, A ^{[1
]}

MARUMO, S ^{[1
]}

WADA, Y ^{[1
]}

YAMAZAKI, I ^{[1
]}

YAMAZAKI, T ^{[1
]}

SHIRAKAWA, Y ^{[1
]}

NISHIMURA, Y ^{[1
]}

机构：

[1] HOKKAIDO UNIV, FAC ENGN, DEPT CHEM PROC ENGN, SAPPORO, HOKKAIDO 060, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1995年 / 68卷 / 10期

关键词：

D O I：

10.1246/bcsj.68.2909

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,3-Dioxane-bridged pyropheophorbide-diimide dyads and pyropheophorbide dimer were synthesized by simple acid-catalyzed reactions of methyl pyropheophorbide d with diimide-substituted diols and with pentaerythritol, respectively. 1,3-Dioxane-bridged bacteriopyropheophorbide-diimide was similarly prepared from bacteriopyropheophorbide a. Intramolecular electron-transfer and energy-transfer reactions in these models have been studied by picosecond fluorescence measurements.

引用

页码：2909 / 2915

页数：7

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