SYNTHESIS OF 1-ARYLALK-2-ENES AND 1-ARYLALKANES VIA FRIEDEL-CRAFTS ALKYLATION WITH ALLYLIC ALCOHOLS CATALYZED BY AN ACIDIC CLAY

被引：22

作者：

SMITH, K

POLLAUD, GM

机构：

[1] Department of Chemistry, University of Wales Swansea

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 24期

关键词：

D O I：

10.1039/p19940003519

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Moderately activated benzenoid compounds undergo alkylation with allylic alcohols in the presence of acidic K10 clay to give almost exclusively 1-arylalk-2-enes by attack at the-terminal position of the intermediate allyl cation; catalytic hydrogenation yields the corresponding 1-arylalkanes.

引用

页码：3519 / 3520

页数：2

共 25 条

[1] MONTMORILLONITE SUPPORTED TRANSITION-METAL SALTS AS FRIEDEL-CRAFTS ALKYLATION CATALYSTS [J].