A NOVEL HONEYCOMB-LIKE COPPER(II) PHOSPHATE FRAMEWORK, [BACL][CUPO4]

被引：32

作者：

ETHEREDGE, KMS ^{[1
]}

HWU, SJ ^{[1
]}

机构：

[1] RICE UNIV,DEPT CHEM,HOUSTON,TX 77251

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 11期

关键词：

D O I：

10.1021/ic00115a051

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Copper(II) phosphates exhibit attractive and unusual frameworks rarely seen in early transition metal phosphates. A wave-like [CuP2O7]infinity ribbon, made of CuO4 and P2O7 units, has been recognized earlier in the Na2CuP2O7 structure. The title compound shows a novel honeycomb-like lattice consisting of a low-dimensional [CuPO4]infinity spiral structure that is constructed of CuO4 and PO4 units. [GRAPHICS] CS]

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页码：3123 / 3125

页数：3

相关论文

共 28 条

[1] THE CRYSTAL-STRUCTURE OF CA3CU3(PO4)4 [J].

ANDERSON, JB ;

KOSTINER, E ;

RUSZALA, FA .

JOURNAL OF SOLID STATE CHEMISTRY, 1981, 39 (01) :29-34

[2] CRYSTAL-STRUCTURE OF CU4(PO4)2O [J].

ANDERSON, JB ;

SHOEMAKER, GL ;

KOSTINER, E .

JOURNAL OF SOLID STATE CHEMISTRY, 1978, 25 (01) :49-57

[3]

BEIN T, 1992, ACS S SERIES, V499

[4] BOND-VALENCE PARAMETERS FOR SOLIDS [J].

BRESE, NE ;

OKEEFFE, M .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197

[5] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[6] CRYSTAL-STRUCTURE OF CU5O2(PO4)2 [J].

BRUNELLAUGT, M ;

GUITEL, JC .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (NOV) :3465-3468

[7]

BRUNELLAUGT M, 1978, J SOLID STATE CHEM, V25, P39, DOI 10.1016/0022-4596(78)90041-5

[8]

Cromer D.T., 1974, INT TABLES CRYSTALLO, V4, P71

[9] KCU4(PO4)3 - A COMPOUND WITH 2 TRIGONAL DIPYRAMIDAL CU(II)O5 COORDINATION POLYHEDRA [J].

EFFENBERGER, H .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1987, 180 (1-4) :43-50

[10] SYNTHESIS OF A NEW LAYERED SODIUM COPPER(II) PYROPHOSPHATE, NA2CUP2O7, VIA AN EUTECTIC HALIDE FLUX [J].

ETHEREDGE, KMS ;

HWU, SJ .

INORGANIC CHEMISTRY, 1995, 34 (06) :1495-1499