A WALL JET ELECTRODE FOR INSITU ELECTROCHEMICAL ESR

被引：8

作者：

COMPTON, RG

GREAVES, CR

WALLER, AM

机构：

[1] Physical Chemistry Laboratory, Oxford University, Oxford, OX1 3QZ, South Parks Road

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 277卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(90)85092-J

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A novel cell suitable for in-situ electrochemical ESR is described. This is based upon a wall-jet design and is shown to function as a satisfactory hydrodynamic electrode. The cell can be located within an ESR cavity without appreciable perturbation of the sensitivity of the ESR technique allowing the measurement of high quality ESR spectra of electrogenerated radicals. © 1990.

引用

收藏

页码：83 / 92

页数：10

相关论文

共 29 条

[1] THE WALL-JET RING-DISC ELECTRODE .1. THEORY [J].

ALBERY, WJ ;

BRETT, CMA .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1983, 148 (02) :201-210

[2] SIMULTANEOUS ELECTROCHEMICAL-ELECTRON SPIN-RESONANCE MEASUREMENTS WITH A COAXIAL MICROWAVE CAVITY [J].

ALLENDOERFER, RD ;

MARTINCHEK, GA ;

BRUCKENSTEIN, S .

ANALYTICAL CHEMISTRY, 1975, 47 (06) :890-894

[3] COAXIAL MICROWAVE CAVITY FOR IMPROVED ELECTRON-PARAMAGNETIC RESONANCE SENSITIVITY WITH LOSSY SOLVENTS [J].

ALLENDOERFER, RD ;

CARROLL, JB .

JOURNAL OF MAGNETIC RESONANCE, 1980, 37 (03) :497-508

[4] ELECTROCHEMICAL GENERATION OF FREE-RADICALS IN AN ELECTRON-PARAMAGNETIC-RES LOOP-GAP RESONATOR [J].

ALLENDOERFER, RD ;

FRONCISZ, W ;

FELIX, CC ;

HYDE, JS .

JOURNAL OF MAGNETIC RESONANCE, 1988, 76 (01) :100-105

[5] A NEWLY DESIGNED VARIABLE TEMPERATURE STATIONARY AND FLOW-THROUGH CELL FOR INSITU ESR-ELECTROCHEMICAL EXPERIMENTS IN SOLVENTS HAVING EITHER LOW OR HIGH DIELECTRIC-CONSTANTS [J].

BAGCHI, RN ;

BOND, AM ;

SCHOLZ, F .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 252 (02) :259-267

[6] TRACE-METAL ANALYSIS IN HYDROPONIC SOLUTIONS [J].

BRETT, CMA ;

NETO, MMPM .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 :1071-1079

[7]

Coetzee J.F., 1982, RECOMMENDED METHODS, P10

[8] PHOTO-ELECTROCHEMICAL ELECTRON-SPIN-RESONANCE .1. EXPERIMENTAL [J].

COLES, BA ;

COMPTON, RG .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1983, 144 (1-2) :87-98

[9]

COLES BR, COMMUNICATION

[10] INSITU ELECTROCHEMICAL ELECTRON-SPIN-RESONANCE - ECE VERSUS DISP1 [J].

COMPTON, RG ;

DALY, PJ ;

UNWIN, PR ;

WALLER, AM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1985, 191 (01) :15-29