ROTATIONAL LINE-STRENGTHS IN THE 3-SIGMA+- 3-SIGMA-+ ORBITALLY FORBIDDEN ELECTRIC-DIPOLE TRANSITIONS

被引：5

作者：

BELLARY, VP

BALASUBRAMANIAN, TK

机构：

[1] Spectroscopy Division, Bhabha Atomic Research Centre, Bombay, 400 085, Trombay

来源：

JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER | 1991年 / 45卷 / 05期

关键词：

D O I：

10.1016/0022-4073(91)90012-F

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Expressions have been developed for the branch intensity factors of orbitally forbidden electric dipole transitions of the type 3-SIGMA +/- -3-SIGMA -/+ in diatomic molecules. It is shown that, in general, the line intensities are governed by the following 13 transition moments: three vibronic moments reflecting spin-orbit effects, six rovibronic moments due to orbit-rotation interaction and four higher-order cross-moments of relatively smaller magnitude. Some special cases are discussed and a few useful sum rules of general validity are established.

引用

页码：283 / 289

页数：7

共 13 条

[1]

Balasubramanian T. K., 1988, Acta Physica Hungarica, V63, P249

[2] ON THE ROTATIONAL INTENSITY DISTRIBUTION IN THE A1-DELTA-G-]X3-SIGMA-G- MAGNETIC DIPOLE TRANSITION OF OXYGEN MOLECULE [J].