ISOTACTIC POLYMETHOXY-1-ALKENES FROM BLUE-GREEN-ALGAE - SYNTHESIS AND ABSOLUTE STEREOCHEMISTRY

被引：56

作者：

MORI, Y ^{[1
]}

KOHCHI, Y ^{[1
]}

SUZUKI, M ^{[1
]}

CARMELI, S ^{[1
]}

MOORE, RE ^{[1
]}

PATTERSON, GML ^{[1
]}

机构：

[1] UNIV HAWAII,DEPT CHEM,HONOLULU,HI 96822

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 02期

关键词：

D O I：

10.1021/jo00002a027

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel isotactic polymethoxy-1-alkenes 1-4 were isolated from tolytoxin-producing blue-green algae belonging to the family Scytonemataceae. Scytonema mirabile produced 1 and 2, whereas 3 and 4 were isolated from S. burmanicum. The gross structures and relative stereochemistries were determined by mass and NMR spectral analyses. The absolute configurations of 1-4 were established by direct comparison with optically active synthetic samples.

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页码：631 / 637

页数：7

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