ABSORPTION-SPECTRA OF TRIALKYLSILYL RADICALS BY A CHEMICAL MODULATION EXPERIMENT

被引：7

作者：

BRIX, T ^{[1
]}

PAUL, U ^{[1
]}

POTZINGER, P ^{[1
]}

REIMANN, B ^{[1
]}

机构：

[1] MAX PLANCK INST STRAHLENCHEM,W-4330 MULHEIM,GERMANY

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1990年 / 54卷 / 01期

关键词：

D O I：

10.1016/1010-6030(90)87003-T

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The absorption spectra of the trimethyl-, triethyl- and tri-n-propylsilyl radicals, generated by the mercury-sensitized photolysis of the corresponding silanes, were observed in a chemical modulation experiment. The absorption cross-section of the trimethylsilyl radical was measured, the value obtained being σ (260 nm, base e) = 3 × 10-17 cm2 per molecule. © 1990.

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页码：19 / 25

页数：7

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