PREPARATION AND STRUCTURE OF THALLIUM(I) 2,4,6-TRIS(TRIFLUOROMETHYL)THIOPHENOLATE, A COMPOUND WITH A FOLDED POLYMERIC STRUCTURE

被引：16

作者：

LABAHN, D ^{[1
]}

POHL, E ^{[1
]}

HERBSTIRMER, R ^{[1
]}

STALKE, D ^{[1
]}

ROESKY, HW ^{[1
]}

SHELDRICK, GM ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 05期

关键词：

THALLIUM COMPOUND; POLYMERIC STRUCTURE; ORGANO FLUORINE LIGAND;

D O I：

10.1002/cber.19911240522

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, thallium(I) 2,4,6-tris(trifluoromethyl)thiophenolate (1) has been prepared by using either TlOEt and (CF3)3C6H2SH or Tl2CO3 and (CF3)3C6H2SNa. A single X-ray structural analysis shows a folded polymeric structure for 1; the crystal lattice incorporates half of a 1,4-dioxane molecule per Tl atom. This compound has a surprisingly high kinetic stability compared to known thallium(I) thiolates.

引用

页码：1127 / 1129

页数：3

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