TRANS-DICHLORO(O,O'-DIETHYLDITHIOPHOSPHATO-S,S')BIS(DIMETHYLPHENYLPHOSPHINE)TECHNETIUM(III)

被引：2

作者：

ABRAM, U ^{[1
]}

ABRAM, S ^{[1
]}

DILWORTH, JR ^{[1
]}

机构：

[1] UNIV ESSEX,DEPT CHEM & BIOL CHEM,COLCHESTER CO4 3SQ,ESSEX,ENGLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷 / pt 10期

关键词：

D O I：

10.1107/S0108270195005063

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [TcCl2(C4H10O2PS2)(C8H11P)(2)], is formed during the reaction of [TcNCl2(Me(2)PhP)(3)] with excess sodium diethyldithiophosphate involving cleavage of the technetium-nitrido bond. The Cl ligands are trans with respect to each other, with a mean TcCl distance of 2.3545 (6) Angstrom. The diethyldithiophosphate is bonded as a chelate ligand with Tc-S bond lengths of 2.4639(7) and 2.4787(6) Angstrom.

引用

页码：1983 / 1985

页数：3

共 9 条

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