REDUCTION OF (MU-2-TE2)FE2(CO)6 AND REACTION OF THE DIANION FORMED WITH METAL DIHALIDES, L2MCL2, (L = PPH3, M = PT, PD, NI, L = C5H5, M = TI, L = ME, NORMAL-BU, M = SN)

被引：26

作者：

MATHUR, P

REDDY, VD

机构：

[1] Chemistry Department, Indian Institute of Technology, Powai, Bombay

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 385卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)85007-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of a THF solution of (μ2-Te2)Fe2(CO)6 with LiEt3BH at -78°C gives the dianion [(μ-Te)2Fe2(CO)6]2-. The dianion reacts with the metal dihalides (PPh3)2MCl2, M = Pt, Pd, Ni, to give the neutral compounds (CO)6Fe2(μ3-Te)2M(PPh3)2, with Cp2TiCl2 to give (CO)6Fe2(μ3-Te)2TiCp2, or with R2SnCl2, R = Me, n-Bu to give (CO)6Fe2(μ3-Te)2SnR2. © 1990.

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页码：363 / 368

页数：6

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