SYNTHESIS AND ELECTRONIC AND MAGNETIC CHARACTERIZATION OF THE TERNARY NITRIDE (FE0.8MO0.2)MON2

被引：34

作者：

BEM, DS ^{[1
]}

OLSEN, HP ^{[1
]}

ZURLOYE, HC ^{[1
]}

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

CHEMISTRY OF MATERIALS | 1995年 / 7卷 / 10期

关键词：

D O I：

10.1021/cm00058a011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The new layered ternary transition metal nitride (Fe0.8Mo0.2)MoN2 has been synthesized in a single-step reaction by the ammonolysis of the transition-metal oxide, Fe-2(MoO4)(3). Powder X-ray diffraction data were collected and the structure was refined using the Rietveld method (P81c, a 2.8562(1) Angstrom, c 10.9997(4) Angstrom). The structure consists of alternating layers of MN(6) (M = Mo:Fe (1:4)) octahedra and M'N-6 (M' = Mo) trigonal prisms. The magnetic susceptibility data. display a maximum at 20 K. Four-probe conductivity measurements indicate poor metallic conductivity with a very small temperature dependence.

引用

页码：1824 / 1828

页数：5

共 42 条

[1] BANASZAK MM, 1990, J AM CHEM SOC, V112, P7989
[2] SYNTHESIS OF INTERMETALLIC NITRIDES BY SOLID-STATE PRECURSOR REDUCTION
BEM, DS
GIBSON, CP
LOYE, HCZ
[J]. CHEMISTRY OF MATERIALS, 1993, 5 (04) : 397 - 399
[3] SYNTHESIS OF THE NEW TERNARY TRANSITION-METAL NITRIDE FEWN2 VIA AMMONOLYSIS OF A SOLID-STATE OXIDE PRECURSOR
BEM, DS
LOYE, HCZ
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1993, 104 (02) : 467 - 469
[4] BEM DS, IN PRESS INORG CHEM
[5] BEM DS, 1993, SOFT CHEM ROUTES NEW, P183
[6] BEM DS, 1995, UNPUB
[7] BEM DS, 1993, MATER RES SOC S P, V327, P150
[8] SYNTHESIS AND CRYSTAL-STRUCTURE OF A MIXED-VALENT LITHIUM-TANTALUM NITRIDE LI2TA3N5
BROKAMP, T
JACOBS, H
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1991, 176 (01) : 47 - 60
[9] BROWN ID, 1992, ACTA CRYSTALLOGR B, V48, P533
[10] SYNTHESIS, STRUCTURE, AND PROPERTIES OF CA2ZNN2
CHERN, MY
DISALVO, FJ
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1990, 88 (02) : 528 - 533

← 1 2 3 4 5 →