APPLICATION OF ELECTROSPRAY MASS-SPECTROMETRY FOR CHARACTERIZING SUPRAMOLECULAR COORDINATION-COMPLEXES

被引：64

作者：

HOPFGARTNER, G ^{[1
]}

PIGUET, C ^{[1
]}

HENION, JD ^{[1
]}

WILLIAMS, AF ^{[1
]}

机构：

[1] UNIV GENEVA,DEPT INORGAN ANALYT & APPL CHEM,CH-1211 GENEVA 4,SWITZERLAND

来源：

HELVETICA CHIMICA ACTA | 1993年 / 76卷 / 04期

关键词：

D O I：

10.1002/hlca.19930760432

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Electrospray Mass Spectrometry (ES-MS) of eight different supramolecular complexes shows that the molecular peaks of the desolvated multiply charged cations can be recorded more easily than by Fast-Atom-Bombardment Mass Spectrometry (FAB-MS) measurements of similar compounds. The preliminary application of the ES-MS technique to self-assembled helical complexes obtained from ligands L3 to L8 with various metal ions (Cu, Co, Eu, Tb) indicates that ES mass spectra qualitatively reflect the species present in MeCN solution.

引用

页码：1759 / 1766

页数：8

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