A NEW CLASS OF S-BRIDGED PENTANUCLEAR COMPLEXES WITH A TRIPLE HELICAL CHIRALITY - CRYSTAL-STRUCTURE OF [(RHIII(AET)3)2(HGIICL2)3] (AET = 2-AMINOETHANETHIOLATE)

被引：24

作者：

OKAMOTO, K ^{[1
]}

KONNO, T ^{[1
]}

KAGEYAMA, Y ^{[1
]}

HIDAKA, J ^{[1
]}

机构：

[1] UNIV TSUKUBA, DEPT CHEM, TSUKUBA, IBARAKI 305, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 06期

关键词：

D O I：

10.1246/cl.1992.1105

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of fac(S)-[Rh(aet)3] (aet = 2-aminoethanethiolate) with HgX2 (X = Cl or NO3) gave twisted-ellipsoid-type S-bridged pentanuclear complexes with a triple helical chirality, in which two DELTA- or LAMBDA-fac(S)-[Rh(aet)3] subunits are linked by three mercury atoms. The crystal structure of [{Rh(aet)3}2(HgCl2)3] was determined by X-ray crystallography.

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页码：1105 / 1108

页数：4

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