DIASTEREOSELECTIVE FLUORINATION AT BENZYLIC POSITION BY ANODIC-OXIDATION

被引：31

作者：

KABORE, L ^{[1
]}

CHEBLI, S ^{[1
]}

FAURE, R ^{[1
]}

LAURENT, E ^{[1
]}

MARQUET, B ^{[1
]}

机构：

[1] UNIV LYON 1,CHIM ANALYT LAB 2,F-69622 VILLEURBANNE,FRANCE

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(00)94714-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By anodic oxidation of benzylic derivatives 1 in Et3N,3HF/CH3CN, diastereoselective fluorination in the α position of the electron withdrawing group is obtained. The observed stereoselectivities are discussed in connection with the inductor group. The role of the anode is also examined. © 1990.

引用

页码：3137 / 3140

页数：4

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