ANALYTICAL SOLUTION OF WERTHEIMS OZ EQUATION FOR THE SMITH-NEZBEDA MODEL OF ASSOCIATED LIQUIDS

被引：36

作者：

KALYUZHNYI, YV

NEZBEDA, I

机构：

[1] Institute of Physics of Condensed Matter, Ukrainian Academy of Sciences, Lwow, 290005

[2] Institute of Chemical Process Fundamentals, Czechoslovak Academy of Sciences, Prague, CZECH

来源：

MOLECULAR PHYSICS | 1991年 / 73卷 / 03期

关键词：

D O I：

10.1080/00268979100101481

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A method enabling one to find an approximate analytical solution of Wertheim's OZ equation for the one-site model of associated liquids is proposed. The resulting average centre-centre pair correlation function agrees with the numerical solution and the same also holds true for the internal energy. The approximate nature of the solution is reflected in the compressibility factor, which slightly underestimates the numerical results.

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页码：703 / 713

页数：11

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