ELECTROCHEMICAL PROPERTIES OF AN ELECTROSYNTHESIZED POLY(PARA-PHENYLENE VINYLENE) FILM AND ITS APPLICATION TO A SIMPLE ELECTROCHEMICAL FABRICATION OF A POLYMER DIODE

被引：7

作者：

NISHIHARA, H

AKASAKA, M

TATEISHI, M

ARAMAKI, K

机构：

来源：

CHEMISTRY LETTERS | 1992年 / 10期

关键词：

D O I：

10.1246/cl.1992.2061

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclic voltammetry of a poly(p-phenylene vinylene) (PPV) film prepared by electrochemical reduction of alpha,alpha,alpha',alpha'-tetrabromo-p-xylene at Pt in THF shows an oxidation wave at ca. +0.8 V and a reduction wave at ca. -1.8 V vs. Ag/Ag+ in 1 mol dm-3 n-Bu4NBF4-MeCN. A polymer diode comprising cathodically polymerized PPV and anodically polymerized polypyrrole (PPy) can be fabricated by the simple one-pot electrochemical procedure.

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页码：2061 / 2064

页数：4

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