ORIGIN OF THE STABILIZATION OF VINYLDIAZONIUM IONS BY BETA-SUBSTITUTION - 1ST CRYSTAL-STRUCTURE OF AN ALIPHATIC DIAZONIUM ION - BETA,BETA-DIETHOXYETHENEDIAZONIUM HEXACHLOROANTIMONATE

被引：25

作者：

GLASER, R

CHEN, GS

BARNES, CL

机构：

[1] Department of Chemistry, University of Missouri, Columbia, Missouri

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 06期

关键词：

D O I：

10.1002/anie.199207401

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The considerable contributions of the O-stabilized mesomeric resonance structures III and IV probably account for the extraordinary stability of the cation of the title compound and related systems. This is apparent from comparisons of the bond lengths and angles of the first experimentally determined structure with the results of ab initio studies. The title compound is prepared by alkylation of diazoacetate with triethyloxonium hexachloroantimonate.

引用

页码：740 / 743

页数：4

共 35 条

[1]

AVARO M, 1968, J CHEM SOC CHEM COMM, P410

[2] ALKENE-DIAZONIUM SALTS - NEW CHAPTER OF CLASSICAL ORGANIC-CHEMISTRY [J].