TOTAL SYNTHESIS OF (+/-)-CLAVIZEPINE

被引：19

作者：

ISHIBASHI, H

TAKAGAKI, K

IMADA, N

IKEDA, M

机构：

[1] Kyoto Pharmaceutical University, Kyoto, 607, Misasagi, Yamashina

来源：

TETRAHEDRON | 1994年 / 50卷 / 34期

关键词：

D O I：

10.1016/S0040-4020(01)81754-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first total synthesis of benzopyranobenzazepine alkaloid (+/-)-clavizepine (1) has been achieved by using the Bradsher cyclization of the keto ester 16 (leading to 18) and the Pummerer-type cyclization of the sulfoxide 25 (leading to 26) as the key steps.

引用

页码：10215 / 10224

页数：10

共 16 条

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