SYNTHESIS OF THE NEW ORGANOMETALLIC CARBOXYLIC-ACID COMPLEXES [(ETA(5)-C5H4COOH)M(CO)NME](M=MO,N=3 M=FE,N=2) AND THEIR POTENTIAL AS BIOCONJUGATES

被引：13

作者：

ELMOUATASSIM, B ^{[1
]}

AMOURI, H ^{[1
]}

SALMAIN, M ^{[1
]}

JAOUEN, G ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM, 11 RUE PIERRE & MARIE CURIE, F-75231 PARIS 05, FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 479卷 / 1-2期

关键词：

IRON; MOLYBDENUM; CARBOXYLIC ACID DERIVATIVES; CYCLOPENTADIENYL DERIVATIVES;

D O I：

10.1016/0022-328X(94)84121-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new compounds [(eta5-C5H4COOH)M(CO)nMe] [M = Mo, n = 3 (2); M = Fe, n = 2 (5)] were synthesized in 61 % and 63% yields, respectively, and treated with N-hydroxysuccinimide to yield the corresponding activated ester derivatives [(eta5-C5H4COONS)-M(CO)nMe] [M = Mo, n = 3 (3); M = Fe, n = 2, (6)]. The metal-activated ester complex, [(eta5-C5H5)Mo(CO)3(CH2COONS)] (8) was obtained similarly, the ester unit being bonded directly to the metal rather than to the pi-bonded cyclopentadienyl. The reactivity and potential of the above species as labelling agents for amino-acids is discussed.

引用

页码：C18 / C20

页数：3

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