KINETICS OF CATALYTIC-OXIDATION OVER PALLADIUM OF SOME ALKANES AND CYCLOALKANES

被引：23

作者：

CULLIS, CF

NEVELL, TG

机构：

[1] CITY UNIV LONDON,DEPT CHEM,LONDON EC1V 4PB,ENGLAND

[2] PORTSMOUTH POLYTECH,DEPT CHEM,PORTSMOUTH PO1 3QL,ENGLAND

来源：

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 1976年 / 349卷 / 1659期

关键词：

D O I：

10.1098/rspa.1976.0087

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 [理学]; 0710 [生物学]; 09 [农学];

摘要：

Measurements have been made of the kinetics of oxidation over palladium of the C//1 to C//4 alkanes, cyclopropane and cyclohexane in the temperature range 588-873 K by means of a microcalorimetric bead technique. With an initially reduced and degassed catalyst, reaction rates for the alkanes increase from C//1 to C//4, while butane, cyclopropane and cyclohexane are of comparable reactivity. The rates of oxidation of the alkanes are significantly increased when the catalyst is preheated in oxygen, and cyclopropane oxidation is markedly enhanced by this procedure.

引用

页码：523 / 534

页数：12

共 14 条

[1]

BAKER AR, 1959, 162 MIN POW SAF MIN

[2]

BORESKOV GK, 1966, DISCUSS FARADAY SOC, V41, P263

[3]

OXIDATION OF CARBON-MONOXIDE CATALYZED BY PALLADIUM [J].