A PRACTICAL SYSTEM FOR MANGANESE(III)-MEDIATED ELECTROCHEMICAL SYNTHESIS OF SORBIC ACID PRECURSORS

被引：22

作者：

COLEMAN, JP

HALLCHER, RC

MCMACKINS, DE

ROGERS, TE

WAGENKNECHT, JH

机构：

[1] Monsanto Company, St. Louis, MO 63167

来源：

TETRAHEDRON | 1991年 / 47卷 / 4-5期

关键词：

D O I：

10.1016/S0040-4020(01)87070-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient, practical, electrochemical system was developed for the synthesis of a mixture of 4-acetoxy-5-hexenoic acid and trans-6-acetoxy-4-hexenoic acid via manganese(III)-mediated oxidation of acetic acid-acetic anhydride in the presence of butadiene. Copper(II) co-catalyst enhanced the efficiency of this oxidation and copper(I) was shown to catalyze in situ conversion of the acetoxyhexenoic acids into gamma-vinyl-gamma-butyrolactone.

引用

页码：809 / 829

页数：21

共 26 条

[1] MANGANESE(III) COMPLEXES IN OXIDATIVE DECARBOXYLATION OF ACIDS [J].