DIMERIC ALKALI-METAL BENZAMIDINATES - INFLUENCE OF THE METAL-ION ON STRUCTURE

被引：80

作者：

STALKE, D ^{[1
]}

WEDLER, M ^{[1
]}

EDELMANN, FT ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 431卷 / 01期

关键词：

D O I：

10.1016/0022-328X(92)83291-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The molecular structures of two N-silylated alkali metal benzamidinates, [MeC6H4C(NSiMe3)2-Li(THF)]2 (1) and [PhC(NSiMe3)2Na(Et2O)]2.Et2O (2), have been determined by low temperature X-ray diffraction studies. Both compounds are dimeric in the solid state but the molecular structures are strongly influenced by the alkali metal used. The Na-Na distance in 2 is unusually short (274.1 pm). The preparation of K[PhC(NSiMe3)2] (3) is also described.

引用

页码：C1 / C5

页数：5

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