A GENERAL-METHOD FOR ITERATIVE CYCLOPENTANNULATION - SEQUENTIAL USE OF CLAISEN REARRANGEMENT AND RADICAL ENYNE CLOSURE

被引：11

作者：

CLIVE, DLJ

MANNING, HW

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 08期

关键词：

D O I：

10.1039/c39930000666

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cycloalkenyl acetylenes 4, which are easily prepared from allylic alcohols 1, undergo radical cyclization (4 --> 5) on treatment with stannyl radicals; the products 5 are themselves convertible into allylic alcohols, so that the annulation sequence can be repeated.

引用

页码：666 / 667

页数：2

共 44 条

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