A CONTRIBUTION TO THE THERMAL-DECOMPOSITION OF SALTS AND METAL-COMPLEXES OF 1, 1-DITHIOLATES

被引：4

作者：

ALY, AAM

机构：

[1] Chemistry Department, Faculty of Science, Assiut University, Assiut

来源：

TRANSITION METAL CHEMISTRY | 1991年 / 16卷 / 02期

关键词：

D O I：

10.1007/BF01032846

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The thermal decomposition of salts and metal complexes (binary and mixed ligand) of dithiocarbamates, xanthates, dithiocarbazates and dithiophosphates has been studied thermogravimetrically. The activation energies of decomposition for some of them were calculated adopting the Coats and Redfern equation. In most cases the binary complexes decompose in a single sharp stage whereas the mixed ligand complexes are characterised by decompositions having more than one stage.

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页码：249 / 251

页数：3

相关论文

共 21 条

[1] CHARACTERIZATION OF SOME NEW NICKEL(II) DITHIOLATO MIXED-LIGAND COMPLEXES WITH NITROGEN DONOR LIGANDS - MAGNETIC, SPECTRAL, AND THERMAL STUDIES [J].

ALY, AAM ;

ELMELIGY, MS ;

ZIDAN, ASA ;

ELSHABASY, M .

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1987, 17 (03) :257-274

[2] ORGANOMERCURY(II) DITHIOCARBAZATES - SYNTHESIS, CHARACTERIZATION AND BIOLOGICAL STUDIES [J].

BHATIA, S ;

KAUSHIK, NK ;

SODHI, GS .

INORGANICA CHIMICA ACTA, 1987, 127 (02) :141-146

[3] ELECTRONIC STRUCTURES OF SQUARE-PLANAR METAL COMPLEXES .2. COMPLEXES OF MALEONITRILEDITHIOLATE WITH COPPER(2) NICKEL)2) PALLADIUM)2) + PLATINUM)2) [J].

BILLIG, E ;

WATERS, JH ;

GRAY, HB ;

BERNAL, I ;

WILLIAMS, R .

INORGANIC CHEMISTRY, 1964, 3 (05) :663-&

[4]

Cavell K.J., 1973, THERMOCHIM ACTA, V5, P319

[5] KINETIC PARAMETERS FROM THERMOGRAVIMETRIC DATA [J].

COATS, AW ;

REDFERN, JP .

NATURE, 1964, 201 (491) :68-&

[6] SQUARE-PLANAR SULFUR COMPLEXES .6. REACTIONS OF BASES WITH XANTHATES DITHIOCARBAMATES AND DITHIOLATES OF NICKEL(2) [J].

COUCOUVANIS, D ;

FACKLER, JP .

INORGANIC CHEMISTRY, 1967, 6 (11) :2047-+

[7] THERMODYNAMICS OF METAL-LIGAND BOND FORMATION .4. BASE ADDUCTS OF BIS(ETHYLXANTHATO)NICKEL(II) AND BIS(DIALKYLDITHIOPHOSPHATO)NICKEL(II) [J].

DAKTERNIEKS, DR ;

GRADDON, DP .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1971, 24 (12) :2509-+

[8] THE SYNTHESES AND PROPERTIES OF COBALT(II), NICKEL(II) AND COPPER(II) COMPLEXES WITH SOME HETEROCYCLIC DITHIOCARBAMATES [J].

FABRETTI, AC ;

FORGHIERI, F ;

GIUSTI, A ;

PRETI, C ;

TOSI, G .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 86 (02) :127-131

[9] MIXED-LIGAND COMPLEXES OF MANGANESE(III) WITH DITHIOCARBAMATE AND GLYCINE ACETYLACETONE LIGANDS - MAGNETIC, SPECTRAL AND THERMAL STUDIES [J].

GARG, BS ;

SINGH, AL ;

DIXIT, R .

TRANSITION METAL CHEMISTRY, 1988, 13 (05) :351-355

[10] ALKYLXANTHATES OF PHENYLARSENIC(III) [J].

GUPTA, RK ;

RAI, AK ;

MEHROTRA, RC ;

JAIN, VK .

POLYHEDRON, 1984, 3 (06) :721-728