THE ADSORPTION OF NO2 ON AG(111) - A LOW-TEMPERATURE RAIRS STUDY

被引：35

作者：

BROWN, WA ^{[1
]}

GARDNER, P ^{[1
]}

KING, DA ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB2 1EW,ENGLAND

来源：

SURFACE SCIENCE | 1995年 / 330卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/0039-6028(95)00397-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Initial adsorption of NO2 on Ag(111) at 86 K is dissociative and gives rise to the formation of adsorbed O and (NO)(2) dimers. Subsequent adsorption is complex leading to the formation of NO3, NO and N2O3 which coexist on the surface with the O and (NO)(2). Further adsorption then leads to the formation of multilayers of N2O4. The multilayers are seen to desorb at 140 K, in agreement with previous observations.

引用

页码：41 / 47

页数：7

共 20 条

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