Effect of factors on the extraction of boron from slags

被引:43
作者
Zhang, PX
Sui, ZT
机构
[1] Non-Ferrous Metallurgy Department, Northeastern University, Shenyang
来源
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE | 1995年 / 26卷 / 02期
关键词
D O I
10.1007/BF02660977
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effects of slag composition, additive agent, and heat treatment on the crystal morphologies, the crystallization behavior, and the efficiency of extraction of boron (EEB) from slags were investigated by chemical analysis, polarization microscope, and X-ray diffraction (XRD) as well as differential thermal analysis (DTA). The EEB varied with the slag composition. The farther the slag composition deviated from the line between 2MgO . B2O3 and 2MgO . SiO2 in the MgO-B2O3-SiO2 system, the lower the EEB. The EEB was directly related to the precipitating characteristics of the boron component in the slags. The EEB was high if the boron component existed in the form of a crystalline phase, otherwise the EEB was low when boron was in the form of an amorphous phase. The EEB from MgO-Al2O3-CaO-B2O3-SiO2 slag varied with the temperature of heat treatment; the highest EEB appeared at 1100 degrees C. The EEB and the crystallinities were increased by addition of TiO2 and MO(x) (M = Mg, Ca, Fe, Si). The effect of MO(x) was more notable than that of TiO2.
引用
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页码:345 / 351
页数:7
相关论文
共 26 条
[1]  
BEALL GH, 1967, J AM CERAM SOC, V50, P1181
[2]  
BODSWORTH C, 1972, PHYSICAL CHEM IRON S, P67
[3]   EFFECT OF SILICON-CARBIDE ADDITIONS ON THE CRYSTALLIZATION BEHAVIOR OF A MAGNESIA LITHIA ALUMINA SILICA GLASS [J].
COON, DN .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1989, 72 (07) :1270-1273
[4]   DIRECT OBSERVATION OF CRYSTALLIZATION OF LI2O-AL2O3-SIO2 GLASSES CONTAINING TIO2 [J].
DOHERTY, PE ;
LEE, DW ;
DAVIS, RS .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1967, 50 (02) :77-&
[5]  
GOO YC, 1984, AMOURPHOUS PHYSICS, P99
[6]   THERMOCHEMISTRY OF MGO-B2O3 SYSTEM [J].
HAUCK, D ;
MULLER, F .
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-WIESBADEN, 1979, 118 (01) :79-87
[7]   CRYSTALLIZATION OF TITANOSILICATE GLASSES FOR NUCLEAR WASTE IMMOBILIZATION [J].
HAYWARD, PJ ;
VANCE, ER ;
CANN, CD ;
DOERN, DC .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1989, 72 (04) :579-586
[8]   COMPARISON OF THE EFFECTS OF TITANIA AND TANTALUM OXIDE NUCLEATING-AGENTS ON THE CRYSTALLIZATION OF LI2O.AL2O3.6SIO2 GLASSES [J].
HSU, JY ;
SPEYER, RF .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1989, 72 (12) :2334-2341
[9]   CRYSTALLIZATION OF LI2O.AL2O3.6SIO2 GLASSES CONTAINING NIOBIUM PENTOXIDE AS NUCLEATING DOPANT [J].
HSU, JY ;
SPEYER, RF .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1991, 74 (02) :395-399
[10]  
KUZEL HJ, 1963, NEUES JB MINER ABH, V100, P326