ACYLATION OVER CATION-EXCHANGED MONTMORILLONITE

被引：68

作者：

CHICHE, B ^{[1
]}

FINIELS, A ^{[1
]}

GAUTHIER, C ^{[1
]}

GENESTE, P ^{[1
]}

GRAILLE, J ^{[1
]}

PIOCH, D ^{[1
]}

机构：

[1] INST RECH HULES & OLEAGINEUX,CIRAD,DIV CHIM CORPS GRAS,F-34032 MONTPELLIER,FRANCE

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1987年 / 42卷 / 02期

关键词：

CLAY MINERALS - Ion Exchange - KETONES;

D O I：

10.1016/0304-5102(87)85029-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Friedel-Crafts acylation of aromatic compounds (benzene, toluene, xylene) with carboxylic acids (CH//3(CH//2)//nCOOH, n equals 0-14) was performed over cation-exchanged montmorillonites (H** plus , Al**3** plus , Ni**2** plus , Zr**4** plus , Ce**3** plus , Cu**2** plus , La**3** plus ). Yields in ketones were found to be dependent upon the nature of the interlayer cation and on the acid chain length.

引用

页码：229 / 235

页数：7

共 15 条

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