MATHEMATICAL-MODELING OF CHEMICAL CLOCK REACTIONS .1. INDUCTION, INHIBITION AND THE IODATE ARSENIOUS-ACID REACTION

被引：9

作者：

BILLINGHAM, J ^{[1
]}

NEEDHAM, DJ ^{[1
]}

机构：

[1] UNIV E ANGLIA,SCH MATH,NORWICH NR4 7TJ,NORFOLK,ENGLAND

来源：

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 1992年 / 340卷 / 1659期

关键词：

D O I：

10.1098/rsta.1992.0080

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

A clock reaction is a chemical reaction that gives rise to an initial induction period before a significant concentration of one of the chemical species involved is produced. We study three isothermal model reaction schemes that can exhibit clock reaction behaviour in a well-stirred situation. We also identify two types of reaction mechanism that can lead to clock reaction behaviour and indicate which is dominant in each of the model systems that we study. These include a well-known model of the iodate-arsenous-acid reaction.

引用

页码：569 / 591

页数：23

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