WITTIG-TYPE REACTIONS WITH PARTIALLY PROTECTED ALDOSES - SYNTHESIS OF ACYCLIC ALDOOCTENOATES AND OCTENONITRILES WITH E-STEREOCHEMISTRY

被引：8

作者：

LIEVRE, C ^{[1
]}

FRECHOU, C ^{[1
]}

DEMAILLY, G ^{[1
]}

机构：

[1] FAC SCI AMIENS,CHIM ORGAN LAB,VALORISAT GLUCIDES GRP,F-80039 AMIENS,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 36期

关键词：

(CARBOMETHOXYMETHYL)TRIPHENYLPHOSPHONIUM YLIDE; PHOSPHONIUM SALT; METHYL BROMOACETATE; BROMOACETONITRILE; ALDOOCTENOATES; ALDOOCTENONITRILES;

D O I：

10.1016/0040-4039(95)01305-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Mono or di-protected aldoses react with methyl bromoacetate or bromoacetonitrile, in presence of tri-n-butylphosphine and zinc, to give stereoselectively with good yields the corresponding E unsaturated Wittig adducts.

引用

页码：6467 / 6470

页数：4

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