ORGANOLANTHANIDE-CENTERED HYDROAMINATION CYCLIZATION OF AMINOOLEFINS - EXPEDIENT OXIDATIVE ACCESS TO CATALYTIC CYCLES

被引：158

作者：

GAGNE, MR ^{[1
]}

NOLAN, SP ^{[1
]}

MARKS, TJ ^{[1
]}

机构：

[1] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 06期

关键词：

D O I：

10.1021/om00156a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The readily accessible (Me5C5)2Sm and (Me5Cs)2Sm(THF)2 catalyze the hydroaminatton/cyclization of a variety of aminoolefins. Mechanistic observations suggest that the active catalysts are trivalent organo-samarium complexes. © 1990, American Chemical Society. All rights reserved.

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页码：1716 / 1718

页数：3

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