EVIDENCE THAT NONVERTICAL TRIPLET ENERGY-TRANSFER TO FLEXIBLE - PI-SYSTEMS IS A FUNCTION OF SINGLE-BOND AS OPPOSED TO DOUBLE-BOND TORSION - COMPARISON OF 2,3-DIPHENYLNORBORNENE AND CIS-STILBENE

被引：23

作者：

GORMAN, AA ^{[1
]}

BEDDOES, RL ^{[1
]}

HAMBLETT, I ^{[1
]}

MCNEENEY, SP ^{[1
]}

PRESCOTT, AL ^{[1
]}

UNETT, DJ ^{[1
]}

机构：

[1] UNIV MANCHESTER,DEPT CHEM,MANCHESTER M13 9PL,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 14期

关键词：

D O I：

10.1039/c39910000963

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2,3-Diphenylnorbornene and cis-stilbene exhibit essentially identical 'nonvertical' triplet excitation behaviour, in agreement with a mechanism requiring torsion about formal single bonds on the ground-state surface.

引用

页码：963 / 964

页数：2

共 23 条

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