REACTION OF KETENE IMINIUM IONS WITH DIFFERENT OLEFINS - NOVEL PREPARATION OF (+/-)-GRANDISOL, (+/-)-FRAGRANOL AND CORRESPONDING METHYL ETHERS

被引：10

作者：

GRANDGUILLOT, JC

ROUESSAC, F

机构：

来源：

TETRAHEDRON | 1991年 / 47卷 / 28期

关键词：

D O I：

10.1016/S0040-4020(01)87126-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We describe here the preparation of grandisol, fragranol and several related cyclobutanic by-products by procedures employing a [2+2] cycloaddition reaction between an olefine and a ketene-iminium cation generated in situ from an alpha-chloroenamine. The regio- and stereospecificity of these cyclization reactions are studied.

引用

页码：5133 / 5148

页数：16

共 36 条

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