SYNTHESIS AND PROPERTIES OF NONCYCLIC POLYETHER COMPOUNDS .18. A NONCYCLIC POLYETHER CARRIER EXHIBITING MAGNESIUM ION-SELECTIVE TRANSPORT

被引：22

作者：

HIRATANI, K

TAGUCHI, K

SUGIHARA, H

机构：

[1] Industrial Products Research Institute, Tsukuba, Ibaraki, 305, 1-1-4, Higashi

来源：

JOURNAL OF MEMBRANE SCIENCE | 1991年 / 56卷 / 02期

关键词：

LIQUID MEMBRANES; FACILITATED TRANSPORT; MAGNESIUM IONOPHORE;

D O I：

10.1016/S0376-7388(00)80805-4

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

1,2-Bis[3-(omicron-carboxyphenoxy)propoxy]-4-t-butylbenzene has been prepared as a carrier which exhibits magnesium ion-selective transport through liquid membranes. In competitive cation transport, this carrier can transport magnesium ion with excellent selectivity, whereas 1,2-bis[2-(omicron-carboxyphenoxy)ethoxy]-4-t-butylbenzene, which has been prepared for comparison, can selectively transport barium ion. Under various transport conditions the cation transport by this carrier has been investigated. The selectivity for magnesium ion alters with changes of conditions. The cation complex of the carrier has also been prepared and investigated spectroscopically.

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页码：153 / 165

页数：13

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