A CONSTRUCTION PRINCIPLE OF THE K-PHASE BASED ON THE EFFICIENT (O-H)DONOR ...OANION STRUCTURAL FUNCTIONALITY - THE EXAMPLES OF K-(EDT-TTF(CH2OH))2X(X = CLO4-CIRCLE-MINUS AND REO4-CIRCLE-MINUS)

被引:73
作者
BLANCHARD, P
BOUBEKEUR, K
SALLE, M
DUGUAY, G
JUBAULT, M
GORGUES, A
MARTIN, JD
CANADELL, E
AUBANSENZIER, P
JEROME, D
BATAIL, P
机构
[1] UNIV PARIS 11,CNRS,PHYS SOLIDES LAB,F-91405 ORSAY,FRANCE
[2] UNIV NANTES,CNRS,SYNTH ORGAN LAB,F-44072 NANTES,FRANCE
[3] UNIV PARIS 11,CNRS,CHIM THEOR LAB,F-91405 ORSAY,FRANCE
关键词
D O I
10.1002/adma.19920040912
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The search for κ‐phases of conducting and superconducting organic cation radical salts is difficult because it is not yet known which characteristics of the donor molecule are required for this structure to be generated. The figure shown the hydroxy‐methyl‐functionalized non‐centroxymmetrical donor EDT‐TTF(CH2OH), which has been purposely associated with the discrete tetrahedral perchlorate and perrhenate anions to form two new examples of a κ‐phase. (Figure Presented.) Copyright © 1992 Verlag GmbH & Co. KGaA, Weinheim
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页码:579 / 581
页数:3
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