ISOTACHOPHORETIC SEPARATION OF ALKALI AND ALKALINE-EARTH METAL-CATIONS IN WATER-POLYETHYLENE GLYCOL MIXTURES

被引：34

作者：

KANIANSKY, D

ZELENSKY, I

VALASKOVA, I

MARAK, J

ZELENSKA, V

机构：

[1] COMENIUS UNIV, FAC PHARM, DEPT ANALYT CHEM, CS-83232 BRATISLAVA, CZECHOSLOVAKIA

[2] INST RADIOECOL & APPL NUCL TECHNOL, CS-05201 SPISSKA NOVA VES, CZECHOSLOVAKIA

[3] COMENIUS UNIV, FAC SCI, DEPT ANALYT CHEM, CS-84215 BRATISLAVA, CZECHOSLOVAKIA

来源：

JOURNAL OF CHROMATOGRAPHY | 1990年 / 502卷 / 01期

关键词：

D O I：

10.1016/S0021-9673(01)89571-6

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The influence of polyethylene glycol (PEG) on the effective mobilities of alkali and alkaline earth metal cations was investigated. It is shown that appropriate proportions of water and PEG in the leading electrolyte enable a complete separation of this group of cations to be achieved by capillary isotachophoresis (ITP). The high dynamic concentration ranges of the ITP determinations achieved in the operational systems based on water-PEG mixtures are illustrated by practical examples (water samples, urine, aqueous extract of apple flesh). © 1990.

引用

页码：143 / 153

页数：11

共 30 条

[1] ISOTACHOPHORESIS - QUALITATIVE SEPARATION OF CATION MIXTURES
BECKERS, JL
EVERAERT.FM
[J]. JOURNAL OF CHROMATOGRAPHY, 1972, 68 (01): : 207 - &
[2] Everaerts F. M., 1976, ISOTACHOPHORESIS THE
[3] DETERMINATION OF SUBSTANCES AT LOW CONCENTRATIONS IN COMPLEX-MIXTURES BY ISOTACHOPHORESIS WITH COLUMN COUPLING
EVERAERTS, FM
VERHEGGEN, TPEM
MIKKERS, FEP
[J]. JOURNAL OF CHROMATOGRAPHY, 1979, 169 (FEB): : 21 - 38
[4] FANALI S, 1985, PHARMAZIE, V40, P653
[5] STABILITY CONSTANTS OF CYCLIC POLYETHER COMPLEXES WITH UNIVALENT CATIONS
FRENSDORFF, HK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (03) : 600 - +
[6] DETERMINATION OF MAGNESIUM AND CALCIUM-IONS IN SEA-WATER BY CAPILLARY TYPE ISOTACHOPHORESIS
FUKUSHI, K
HIIRO, K
[J]. FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1986, 323 (01): : 44 - 46
[7] DETERMINATION OF POTASSIUM IN SEA-WATER BY CAPILLARY ISOTACHOPHORESIS
FUKUSHI, K
HIIRO, K
[J]. FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1988, 332 (02): : 125 - 129
[8] Fukushi K., 1986, ANAL SCI, V2, P219
[9] CHEMICAL-KINETICS IN ISOTACHOPHORESIS - EFFECTS OF NON-INSTANTANEOUSLY REVERSIBLE COMPLEXING EQUILIBRIA ON THE STABILITY OF ZONES
GEBAUER, P
BOCEK, P
[J]. JOURNAL OF CHROMATOGRAPHY, 1984, 299 (02): : 321 - 330
[10] ISOTACHOPHORESIS OF KINETICALLY LABILE COMPLEXES
GEBAUER, P
BOCEK, P
DEML, M
JANAK, J
[J]. JOURNAL OF CHROMATOGRAPHY, 1980, 199 (OCT): : 81 - 94

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