CONVENIENT PREPARATION OF BINAP RUTHENIUM(II) COMPLEXES CATALYZING ASYMMETRIC HYDROGENATION OF FUNCTIONALIZED KETONES

被引：165

作者：

KITAMURA, M ^{[1
]}

TOKUNAGA, M ^{[1
]}

OHKUMA, T ^{[1
]}

NOYORI, R ^{[1
]}

机构：

[1] NAGOYA UNIV,DEPT CHEM,CHIKUSA KU,NAGOYA,AICHI 464,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 33期

关键词：

D O I：

10.1016/S0040-4039(00)79892-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ligand exchange between [RuCl2(benzene)]2 or RuCl2[Sb(C6H5)3]3 and (R)- or (S)-BINAP produces BINAP-Ru(II) complexes which act as catalysts for the highly enantioselective hydrogenation of functionalized ketones.

引用

页码：4163 / 4166

页数：4

共 13 条

[1] A SIMPLE GENERAL-ROUTE TO CHELATE DIPHOSPHINE RUTHENIUM(II) COMPLEXES
ALCOCK, NW
BROWN, JM
ROSE, M
WIENAND, A
[J]. TETRAHEDRON-ASYMMETRY, 1991, 2 (01) : 47 - 50
[2] GENERAL-SYNTHESIS OF NOVEL CHIRAL RUTHENIUM CATALYSTS AND THEIR USE IN ASYMMETRIC HYDROGENATION
GENET, JP
MALLART, S
PINEL, C
JUGE, S
LAFFITTE, JA
[J]. TETRAHEDRON-ASYMMETRY, 1991, 2 (01) : 43 - 46
[3] NEW EFFICIENT METHODS FOR THE SYNTHESIS AND INSITU PREPARATION OF RUTHENIUM(II) COMPLEXES OF ATROPISOMERIC DIPHOSPHINES AND THEIR APPLICATION IN ASYMMETRIC CATALYTIC HYDROGENATIONS
HEISER, B
BROGER, EA
CRAMERI, Y
[J]. TETRAHEDRON-ASYMMETRY, 1991, 2 (01) : 51 - 62
[4] SYNTHESIS OF NOVEL CHIRAL RUTHENIUM COMPLEXES OF 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL AND THEIR USE AS ASYMMETRIC CATALYSTS
IKARIYA, T
ISHII, Y
KAWANO, H
ARAI, T
SABURI, M
YOSHIKAWA, S
AKUTAGAWA, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (13) : 922 - 924
[5] HOMOGENEOUS ASYMMETRIC HYDROGENATION OF FUNCTIONALIZED KETONES
KITAMURA, M
OHKUMA, T
INOUE, S
SAYO, N
KUMOBAYASHI, H
AKUTAGAWA, S
OHTA, T
TAKAYA, H
NOYORI, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (02) : 629 - 631
[6] A PRACTICAL ASYMMETRIC-SYNTHESIS OF CARNITINE
KITAMURA, M
OHKUMA, T
TAKAYA, H
NOYORI, R
[J]. TETRAHEDRON LETTERS, 1988, 29 (13) : 1555 - 1556
[7] SYNTHESIS OF NEW CATIONIC BINAP-RUTHENIUM(II) COMPLEXES AND THEIR USE IN ASYMMETRIC HYDROGENATION [BINAP = 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]
MASHIMA, K
KUSANO, KH
OHTA, T
NOYORI, R
TAKAYA, H
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (17) : 1208 - 1210
[8] ASYMMETRIC HYDROGENATION OF BETA-KETO CARBOXYLIC ESTERS - A PRACTICAL, PURELY CHEMICAL ACCESS TO BETA-HYDROXY ESTERS IN HIGH ENANTIOMERIC PURITY
NOYORI, R
OHKUMA, T
KITAMURA, M
TAKAYA, H
SAYO, N
KUMOBAYASHI, H
AKUTAGAWA, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (19) : 5856 - 5858
[9] CHIRAL METAL-COMPLEXES AS DISCRIMINATING MOLECULAR CATALYSTS
NOYORI, R
[J]. SCIENCE, 1990, 248 (4960) : 1194 - 1199
[10] BINAP - AN EFFICIENT CHIRAL ELEMENT FOR ASYMMETRIC CATALYSIS
NOYORI, R
TAKAYA, H
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (10) : 345 - 350

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