NOVEL NI0-CATALYZED PREPARATION OF 3-CYCLOPENTENECARBOXYLIC ANILIDES FROM CYCLOPENTENES AND PHENYLISOCYANATE

被引：16

作者：

HOBERG, H

NOHLEN, M

机构：

[1] Max-Planck-Institut für Kohlenforschung, Postfach 101353, Kaiser-Wilhelm-Platz 1

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 382卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(90)85236-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyclopentenes react with isocyanate on (Lig)Ni0-systems to form the bicyclic 5-azanickelacyclopentan-4-one derivates. The geometry of these butterfly complexes favors β-elimination of the β′-hydrogen atoms over that of the β- or β″-hydrogen. In a catalytic reaction the unsaturated amides 3-cyclopentene-carboxylic amide or 2-methylcyclopentene-3-carboxylic amide, both of which are substituted in position 3, are formed with high selectivity. © 1990.

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页码：C6 / C10

页数：5

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